Sublithospheric diamonds: Plate tectonics from Earth's deepest samples (Annual Reviews, 2024)
✦ Group of type IIa rough diamonds (VRL# 190894). These rough diamonds, comprising the world's most valuable gemstones based on size and clarity, are the subject of recent research that shows them to crystallize out of metallic liquids at extreme depths in the mantle. The examples shown here range from 14 to 91 carats sometimes appear to be broken fragments of once larger diamonds. Photo by Robert Weldon. © 2015 GIA. Courtesy of Gem Diamonds Ltd.
✦ DMGC -part of the Reservoirs & Fluxes Directorate of the Deep Carbon Observatory.
✦ Recent studies of large gem diamonds known as CLIPPIR diamonds (such as those in the photo at top) reveal the low redox conditions in the deep mantle allow carbon to segregate from metallic iron, thus confirming theoretical predictions of oxygen activity and providing a new carbon pathway. See Smith et al. (2016) Science 354, 1403-1405. Figure from Smith, Shirey, and Wang, Gems and Gemology 53, 388-403.
Sonja Aulbach, Goethe Univeristat, Germany
Frank Brenker, Goethe Universitat, Germany
Pierre Cartigny, Inst. Physique du Globe, France
Daniel Frost, Beyreuth Geoistitut, Germany
Erik Hauri, Carnegie Inst. for Science, USA
Dorit Jacob, University of Melbourne, Australia
Fabrizio Nestola, University of Padua, Italy
Paolo Nimis, University of Padua, Italy
Graham Pearson, University of Alberta, Canada
Karen Smit, Gemological Inst. of America, USA
Steven Shirey, Carnegie Inst. for Science, USA
Thomas Stachel, University of Alberta, Canada
Emilie Thomassot, ETH, Switzerland
Michael Walter, University of Bristol, UK
pinpointing the onset of plate tectonics at 3.2 Ga
recycling through the mantle transition zone to the top of the lower mantle
observation of the first terrestrial ringwoodite
documentation of mantle methane in diamond growth fluids
establishing the high water carrying capacity of nominally ahnydrous minerals such as ringwoodite
documenting seawater subduction and recent diamond growth
generation of IIa diamonds from deep mantle metallic liquid
verification of metastable reducing conditions in the mantle transition zone
observation of the first terrestrial calcium perovskite
association of deep mantle carbon with pervasive recycling related to slab subduction
What is the source of carbon and other volatiles returned by diamond from the deep mantle?
What is the mineralogy and composition the major deep mantle minerals from direct sample analysis?
What is the mechanism and capacity for water storage in deep mantle minerals?
How and why do contrasting (carbonatitic versus metallic) mantle environments exist?
Does the C and N isotopic composition of diamonds vary with geologic time?
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legacy project on C and N isotopic signatures of diamond-forming fluids through time
future Research in MIneralogy and Geochemistry (RiMG) volume on Diamonds